Synthesis and catalytic application of amino acid based dendritic macromolecules
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Publication date
1999
Authors
Koten, G. van
Gossage, R.A.
Jastrzebski, J.T.B.H.
Ameijde, J. van
Mulders, S.J.E.
Brouwer, Arwin J.
Liskamp, R.M.J.
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Article
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Abstract
The use of amino acid based dendrimers as molecular scaffolds for the attachment of catalytically active organometallic Ni ''pincer'' complexes, via a urea functionality, is described; the dendrimer catalysts have comparable activity to their mononuclear (NCN)NiX analogues.