{2,6-Bis[(dimethylamino-κN)methyl]-4-{[(2,5-dioxo-1-pyrrolidinyl)oxy]carbonyl}phenyl-κC1}(diiodine)iodidoplatinum(II) dichloromethane hemisolvate
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Publication date
2007
Authors
von Chrzanowski, L.S.
Lutz, Martin
Spek, A.L.
Suijkerbuijk, B.M.J.M.
Klein Gebbink, Robertus J.M.
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Abstract
In the title compound [Pt(C17H22N3O4)I(I2)]·0.5CH2Cl2, the coordination environment of the PtII centre is distorted square-pyramidal and is defined by two neutral N atoms and an anionic C atom from the mono-anionic ligand, an iodide anion, and an additional η1-coordinated I2 molecule. Intermolecular C—H...O contacts result in a dimeric structure. The asymmetric unit of (I) consists of two independent [PtI(C17H22N3O4)(I2)] molecules and a CH2Cl2 solvent molecule
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von Chrzanowski, L S, Lutz, M, Spek, A L, Suijkerbuijk, B M J M & Klein Gebbink, R J M 2007, '{2,6-Bis[(dimethylamino-κN)methyl]-4-{[(2,5-dioxo-1-pyrrolidinyl)oxy]carbonyl}phenyl-κC1}(diiodine)iodidoplatinum(II) dichloromethane hemisolvate', Acta crystallographica. Section E, Structure reports, vol. 63, no. 5, pp. m1223-m1225.