Cyclisation, aromatisation and expulsion reactions of β-carotene during sediment diagenesis

Abstract

A novel diaryl isoprenoid 1 with an additional aromatic ring (C30H38), formed from the carotenoid -carotene by cyclisation, aromatisation and expulsion reactions during sediment diagenesis, has been isolated from a 50 Ma old lacustrine sedimentary rock and identified by 1H and 13C NMR spectroscopy and mass spectrometry.

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