Communication: Bulkiness versus anisotropy: The optimal shape of polarizable Brownian nanoparticles for alignment in electric fields

Abstract

Self-assembly and alignment of anisotropic colloidal particles are important processes that can be influenced by external electric fields. However, dielectric nanoparticles are generally hard to align this way because of their small size and low polarizability. In this work, we employ the coupled dipole method to show that the minimum size parameter for which a particle may be aligned using an external electric field depends on the dimension ratio that defines the exact shape of the particle. We show, for rods, platelets, bowls, and dumbbells, that the optimal dimension ratio (the dimension ratio for which the size parameter that first allows alignment is minimal) depends on a nontrivial competition between particle bulkiness and anisotropy because more bulkiness implies more polarizable substance and thus higher polarizability, while more anisotropy implies a larger (relative) difference in polarizability